ABINIT, GW input variables:

List and description.



This document lists and provides the description of the name (keywords) of the GW input variables to be used in the main input file of the abinit code.
The new user is advised to read first the new user's guide, then the abinit help file, before reading the present file. It will be easier to discover the present file with the help of the two lessons lesson_gw1 and lesson_gw2 of the tutorial. Other input variables directly related to the GW computation are : getkss   getscr   optdriver. In case of parallel execution, the input variable gwpara is used to choose between the different parallelization levels presently implemented (k-points or bands).
Note also the Mrgscr utility which allows one to merge dielectric matrices calculated at different q-points into a unique screening file that can be used for subsequent GW calculations.
Copyright (C) 2002-2010 ABINIT group (XG)
This file is distributed under the terms of the GNU General Public License, see ~abinit/COPYING or http://www.gnu.org/copyleft/gpl.txt .
For the initials of contributors, see ~abinit/doc/developers/contributors.txt .

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Files that describe other input variables:
See also the Space group table

Content of the file : alphabetical list of variables.


A. awtr  
B. bdgw  
C.
D.
E. ecuteps   ecutsigx   ecutwfn  
F. fftgw   freqremax   freqspmax  
G. gwcalctyp   gwcomp   gwgamma   gwmem   gwrpacorr   gw_nstep   gw_nqlwl   gw_qlwl   gw_sctype   gw_sigxcore   gw_toldfeig  
H.
I. inclvkb   icutcoul  
J.
K. kptgw  
M.
N. nbandkss   nfreqim   nfreqmidm   nfreqre   nfreqsp   npwkss   nkptgw   nomegasrd   nomegasi   nomegasf   npweps   npwsigx   npwwfn   nsheps   nshsigx   nshwfn  
O. omegasimax   omegasrdmax  
P. ppmfrq   ppmodel  
Q. qptdm  
R. rhoqpmix  
S. soenergy   spbroad   spmeth   symchi   symsigma  
T.
U.
V.
W.
X.
Y.
Z. zcut  




awtr
Mnemonics: evaluate the Adler-Wiser expression of $\chi^{(0)}_{KS}$ assuming Time-Reversal
Characteristic: GW
Variable type: integer parameter
Default 1 (was 0 prior to 5.8)

Only relevant if optdriver=3, that is, screening calculations.

This input variable defines whether the irreducible polarizability $\chi^{(0)}_{KS}$ is evaluated taking advantage of time-reversal symmetry or not.





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bdgw
Mnemonics: BanDs for GW calculation
Characteristic: GW
Variable type: integer array bdgw(2,nkptgw, nsppol,)
Default is all 0's

Only relevant if optdriver=4, that is, sigma calculations.

For each k-point with number ikptgw in the range (1:nkptgw) and each spin index isppol, bdgw(1,ikptgw,isppol) is the number of the lowest band for which the GW computation must be done, and bdgw(2,ikptgw,isppol) is the number of the highest band for which the GW computation must be done.

When gwcalctyp >= 20, the quasiparticle wavefunctions are computed and represented as linear combination of some Kohn-Sham wavefunctions. In this case bdgw designates the KS wavefunctions used as basis set. For each k-point, indeed, the quasiparticle wavefunctions are expanded considering only the KS states between bdgw(1,ikptgw,isppol) and bdgw(2,ikptgw,isppol). Note that the initial values given in the input file might be changed inside the code so that all the degenerate states at a given k-point and spin are included. This might happen when symsigma=1 is used or in the case of self-consistent GW calculations. When symsigma=1, indeed, the diagonal matrix elements of the self-energy are obtained by averaging the unsymmetrized results in the degenerate subspace. For self-consistent calculations, on the other hand, the basis set used to expand the GW wavefunctions should include all the degenerate states belonging to the same irreducible representation. Only in this case, indeed, the initial symmetries and energy degeneracies are preserved.



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ecuteps
Mnemonics: Energy CUT-off for EPSilon (the dielectric matrix)
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

ecuteps determines the cut-off energy of the planewave set used to represent the independent-particle susceptibility $\chi^{(0)}_{KS}$, the dielectric matrix $\epsilon$, and its inverse.
It is not worth to take ecuteps bigger than four times ecutwfn, this latter limit corresponding to the highest Fourier components of a wavefunction convoluted with itself. Usually, even twice the value of ecutwfn might overkill. A value of ecuteps between 5 and 10 Hartree often leads to converged results (at the level of 0.01 eV for the energy gap). In any case, a convergence study is worth.

This set of planewaves can also be determined by the other input variables npweps and nsheps, but these are much less convenient to use for general systems, than the selection criterion based on a cut-off energy.



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ecutsigx
Mnemonics: Energy CUT-off for SIGma eXchange
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0 .

Only relevant if optdriver=4, that is, sigma calculations.

ecutsigx determines the cut-off energy of the planewave set used to generate the exchange part of the self-energy operator. For norm-conserving calculations, it is pointless to have ecutsigx bigger than 4*ecut, while for PAW calculations, the maximal useful value is pawecutdg. Thus, if you do not care about CPU time, please use these values. If you want to spare some CPU time, you might try to use a value between ecut and these upper limits.

This set of planewaves can also be determined by the other input variables npwsigx and nshsigx, but these are much less convenient to use for general systems, than the selection criterion based on the cut-off energy (ecutsigx has to be 0.0 for using these).



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ecutwfn
Mnemonics: Energy CUT-off for WaveFunctions
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0, although, if a screening or self-energy calculation is done (optdriver=3 or 4), ecutwfn is automatically set to ecut

Only relevant if optdriver=3 or 4, that is, screening and sigma calculations.

ecutwfn determines the cut-off energy of the planewave set used to represent the wavefunctions in the formula that generates the independent-particle susceptibility $\chi^{(0)}_{KS}$ (for optdriver=3), or the self-energy (for optdriver=4).
Usually, ecutwfn is smaller than ecut, so that the wavefunctions are filtered, and some components are ignored. As a side effect, the wavefunctions are no more normalized, and also, no more orthogonal. Also, the set of plane waves can be much smaller for optdriver=3, than for optdriver=4, although a convergence study is needed to choose correctly both values.

This set of planewaves can also be determined by the other input variables npwwfn and nshwfn, but these are much less convenient to use for general systems, than the selection criterion based on the cut-off energy (ecutwfn has to be set to 0.0 for using these).



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fftgw
Mnemonics: FFT for GW calculation
Characteristic: GW
Variable type: integer parameter
Default is 21.

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

The basic ingredients needed to perform both a screening and a sigma calculation are the so-called oscillator matrix elements defined as

$< k-q, b1 | e^{-i (q+G).r} | k b2 >$    1)

In reciprocal space, Eq.1 is given by a convolution in which the number of reciprocal lattice vectors employed to describe the wavefunctions is given by ecutwfn Tn the case of screening calculations, the number of G vectors in Eq.1 is defined by ecuteps, while ecutsigx defined the number of G used in sigma calculations. To improve the efficiency of the code, the oscillator matrix elements are evaluated in real space through FFT techniques, and the fftgw input variable is used to select the FFT mesh to be used.

fftgw is the concatenation of two digits, labelled (A) and (B) whose value is internally used to define the value of ngfft(1:3) (see the setmesh.F90 routine).

The first digit (A) defines the augmentation of the FFT grid. Possible values are 1, 2 and 3.

The second digit (B) can be chosen between 0 and 1. It defines whether a FFT grid compatible with all the symmetries of the space group must be enforced or not:

The behaviour of ABINIT before v5.5 corresponds to the default value 11.




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freqremax
Mnemonics: FREQuencies along the Real axis MAXimum
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0

Only relevant if optdriver=3, that is, screening calculations.

freqremax is used only for numerical integration of the GW self-energy (gwcalctyp= 2, 12, 22, 9, 19, 29).
freqremax sets the maximum real frequency used to calculate the dielectric matrix in order to perform the numerical integration of the GW self-energy. freqremax and nfreqre define the spacing of the frequency mesh along the real axis.




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freqspmax
Mnemonics: FREQuencies for the SPectral function MAXimum
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0

Only relevant if optdriver=4, that is, sigma calculations.

freqspmax sets the maximum real frequency used to calculate the spectral function from the GW Green's function. freqspmax and nfreqsp define the spacing of the frequency mesh along the real axis.



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gwcalctyp
Mnemonics: GW CALCulation TYPe
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

gwcalctyp governs the choice between the different capabilities of the GW code.





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gwcomp
Mnemonics: GW COMPletness
Characteristic: GW
Variable type: integer
Default is 0

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

gwcomp governs the use of an extrapolar approximation. If gwcomp==1, one improves the completeness in a truncated sum over states. In practice, this permits one to reduce quite much the number of bands required in the calculation of the screening or of the self-energy. The energy parameter needed in the extrapolar approximation is set by gwencomp. See F. Bruneval, X. Gonze, Phys. Rev. B 78, 085125 (2008) for a description of the methodology.



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gwencomp
Mnemonics: GW Energy for COMPletness
Characteristic: GW
Variable type: energy
Default is 2.

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations, when gwcomp is equal to 1.

gwencomp sets the energy parameter used in the extrapolar approximation used to improve completeness and make the convergence against the number of bands much faster.

See F. Bruneval, X. Gonze, Phys. Rev. B 78, 085125 (2008) for a description of the methodology.



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gwgamma
Mnemonics: GW Gamma
Characteristic: GW
Variable type: integer
Default is 0

Only relevant if optdriver=4, that is, sigma calculations.

If gwgamma is 1, the vertex correction will be included leading to what is known as "GWGamma" approximation. see R. Del Sole, L. Reining, and R. W. Godby, Phys. Rev. B 49, 8024 (1994). Note that, in order to include the vertex correction in W, one has to start the sigma calculation from the susceptibility file_SUSC instead of the _SCR file (see getsuscep   and irdsuscep  ) Not available for PAW calculations.





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gwmem
Mnemonics: GW MEMory
Characteristic: GW
Variable type: integer
Default is 11

Only relevant if optdriver=3,4, that is, sigma calculations.

gwmem governs the memory strategy during a screening and/or a sigma run.

The default is gwmem = 11, which is the fastest, but also the most memory consuming. When experiencing memory shortage, one should try gwmem = 0. The first digit is only meaningful when performing sigma calculations.





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gwrpacorr
Mnemonics: GW RPA CORRelation energy
Characteristic: GW
Variable type: integer
Default is 0

Only relevant if optdriver=3 and if gwcalctyp=x1, i.e. a screening calculation for imaginary frequencies.

gwrpacorr governs the calculation of the RPA correlation energy.





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gw_nstep
Mnemonics: GW Number of self-consistent STEPS
Characteristic: GW
Variable type: integer
Default is 30

Only relevant if optdriver=8, that is, self-consistent GW calculations.

Gives the maximum number of self-consistent GW cycles (or "iterations"). in which G and/or W will be updated until the quasi-particle energied are converged within gw_toldfeig. gwcalctyp and gw_sctype are used to define the type of self-consistency.





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gw_nqlwl
Mnemonics: GW, Number of Q-points for the Long Wave-Length Limit
Characteristic: GW
Variable type: integer
Default is 1

Only relevant if optdriver=3,4 that is, screening or sigma calculations, althought the actual meaning of the variable depends on the particular run-level (see discussion below).

gw_nqlwl defines the number of directions in reciprocal space used to describe the non-analytical behaviour of the heads (G = G'=0) and the wings (G=0 or G'=0) of the dielectric matrix in the optical limit (i.e. for q tending to zero). The number of directions is specified by the additional variable gw_qlwl.

When optdriver=3, gw_nqlwl and gw_qlwl define the set of "small" q that will be calculated and stored in the final SCR file. Therefore, the two variables can be used to analyze how the optical spectra depend on the direction of the incident phonon (useful especially in anisotropic systems). When optdriver=3, gw_nqlwl and gw_qlwl can be used to specify the heads and the wings to be used to perform the quadrature of the correlated part of the self-energy in the small region around the origin. (NB: not yet available, at present the quadrature is performed using a single direction in q-space)





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gw_qlwl
Mnemonics: GW, Q-points for the Long Wave-Length Limit
Characteristic: GW
Variable type: real array gw_qlwl(3,gw_nqlwl)
Default is 0.00001 0.00002 0.00003

Only relevant if optdriver=3,4 that is, screening or sigma calculations.

When optdriver=3, gw_qlwl defines the set of q-points around Gamma that are considered during the evaluation of the non-analytical behaviour of the dielectrix matrix. Optical spectra (with and without non-local field effects) are evaluated for each direction specified by gw_qlwl.





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gw_sctype
Mnemonics: GW, Self-Consistency TYPE
Characteristic: GW
Variable type: integer
Default is 0 so that no choice is done

This variable is used to partially define the kind of self-consistency for GW calculations. The other piece of information is given by gwcalctyp that defines the particular approximation for the self-energy operator as well as whether the wavefunctions have to replaced by quasi-particle amplitudes.

If gw_sctype is specified in the input file, the code will perform an iterative update of the quantities entering the GW equations until the quasi-particle energies are converged within gw_toldfeig. The maximum number of iterations is specified by gw_nstep. Possible values are:

It is possible to initialize the self-consistent procedure by reading a previously calculated SCR or SUSC file via the variables getscr or getsuscep, respectively. getqps can be used to read a previous QPS file thus initializing the Green's functions to be used in the first self-consistent iteration.




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gw_sigxcore
Mnemonics: GW, treatment of the ...
Characteristic: GW
Variable type: integer
Default is 0

Only available for PAW and relevant if optdriver=4 that is, sigma calculations.

Theoretical introduction: GW calculations perfomed on top of electronic calculations relying when the frozen-core approximation is used to separate inner-core electrons from valence electrons, only the contribution to the self-energy arising from valence electrons is explicitly accounted for. In the standard approach based on pseudopotentials the contribution to the self-energy due to core electrons is approximated by means of the KS exchange-correlation potential generated by the core density. In the case of GW calculations employing the PAW method, the core contribution to the self-energy can be more accurately estimated in terms of the Fock operator generated by the core wavefunctions. In the simplest approach, the only ingredients required for this more refined treatment are the wave functions of the core electrons in the reference atomic configuration that are calculated during the generation of the PAW setup. This is a good approximation provided that the core wave functions are strictly localized inside the PAW spheres.

gw_sigxcore defines the approximation used to evaluate the core contribution to sigma.





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gw_toldfeig
Mnemonics: GW TOLerance on the DiFference of the EIGenvalues
Characteristic: GW, ENERGY
Variable type: REAL
Default is 0.1 eV

Sets a tolerance for absolute differences of QP energies that will cause one self-consistent GW cycle to stop.
Can be specified in Ha (the default), Ry, eV or Kelvin, since toldfe has the 'ENERGY' characteristics (1 Ha=27.2113845 eV)
Effective only when self-consistent GW calculations are done (optdriver=8).





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inclvkb
Mnemonics: INCLude VKB
Characteristic: GW
Variable type: integer parameter
Default is 1 TODO: should be changed to 0 or 2

Only relevant if optdriver=3, that is, a screening calculations.

Possible values of inclvkb are 0,1,2. If inclvkb is 1 or 2, the commutator of the non-local part of the Hamiltonian with the position operator is correctly included in the q => 0 contribution. This is unfortunately time-consuming. In case inclvkb is 0, this contribution is incorrectly omitted, but the computation is much faster.

The importance of this contribution depends on the number of k points. Turning off inclvkb should be made by experienced users only.



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icutcoul
Mnemonics: Integer that governs the CUT-off for COULomb interaction
Characteristic: GW
Variable type: integer parameter
Default is 3

(This documentation is still very primitive, and should be checked) Only relevant if optdriver=3 or 4, that is, a screening or self-energy calculation.

Many-body calculations for isolated systems present a slow convergence with respect to the size of the supercell due to the long ranged Coulomb interaction and the high degree of non-locality of the operators involved. A similar issue occur also in fully periodic systems due to the presence of the integrable Coulomb singularity at G=0 that hinders the convergence with respect to the number of q-points used to sample the Brillouin zone. The convergence can be accelerated by replacing the true bare Coulomb interaction with other expressions icutcoul defines the particular expression to be used for the Coulomb term in reciprocal space. The choice of icutcoul depends on the dimensionality of the system. Possible values of icutcoul are 0 to 6. To be complemented by values of vcutgeo and rcut

Note that Spencer and Alavi PRB 77, 193110 (2008) showed that the spherical cutoff can efficiently be used also for 3D systems. In the latter case, use a negative value for the cutoff radius of the sphere (rcut<0), which is automatically calculated so that the volume enclosed in the sphere is equal to the volume of the solid.




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kptgw
Mnemonics: K-PoinTs for GW calculations
Characteristic: GW
Variable type: real array kptgw(3,nkptgw)
Default is all 0.0's

Only relevant if optdriver=4, that is, sigma calculations.

For each k-point with number igwpt in the range (1:nkptgw), kptgw(1,igwpt) is the reduced coordinate of the k-point where GW corrections are required. while bdgw(1:2,igwpt) specifies the range of bands to be considered.

At present, not all k-points are possible. Only those corresponding to the k-point grid defined with the same repetition parameters (kptrlatt, or ngkpt) than the GS one, but WITHOUT any shift, are allowed.



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nbandkss
Mnemonics: Number of BaNDs in the KSS file
Characteristic:
Variable type: integer parameter
Default is 0

This input variable is used for the preparation of a GW calculation : it is used in a GS run (where optdriver=0) to generate a _KSS file. In this run, nbandkss should be non-zero. The generated _KSS file can be subsequently used to calculate the irreducible polarizabilty $\chi^{(0)}_{KS}$ using optdriver=3 or to calculate GW corrections setting optdriver=4.

See npwkss for the selection of the number of the planewave components of the eigenstates to be stored.
The input variable accesswff can be used to read and write KSS files according to different fileformat (presently only accesswff=0 and 3 are available in the GW part).
The precision of the KSS file can be tuned through the input variable kssform.
For more details about the format of the abo_KSS file, see the routine outkss.F90.

Very important : for the time being, istwfk must be 1 for all the k-points in order to generate a _KSS file.



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nfreqim
Mnemonics: Number of FREQuencies along the IMaginary axis
Characteristic:
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3, that is, screening calculations.

nfreqim is used only for numerical integration of the GW self-energy (gwcalctyp= 2, 12, 22, 9, 19, 29).
nfreqim sets the number of pure imaginary frequencies used to calculate the dielectric matrix in order to perform the numerical integration of the GW self-energy.




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nfreqmidm
Mnemonics: Nth FREQuencey moment of the IMaginary part of DM
Characteristic:
Variable type: integer parameter
No default

at the moment only relevant if optdriver=4, that is, a screening calculation.

depending on the value of >nfreqmidm will calculate the frequency moment of the Dielectric matrix or its inverse, if >nfreqmidm positive : calculate (nth=nfreqmidm) frequency moment of the Dielectric matrix if >nfreqmidm negative : calculate (nth=nfreqmidm) frequency moment of the inverse Dielectric matrix if >nfreqmidm = 0 : calculate first frequency moment of the full polarizability see M. Taut, J. Phys. C: Solid State Phys. 18 (1985) 2677-2690.



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nfreqre
Mnemonics: Number of FREQuencies along the Real axis
Characteristic:
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3, that is, screening calculations.

nfreqre is used only for numerical integration of the GW self-energy (gwcalctyp= 2, 12, 22, 9, 19, 29).
nfreqre sets the number of real frequencies used to calculate the dielectric matrix in order to perform the numerical integration of the GW self-energy.

It can be used also in case of GW calculations with plasmon-pole models, i.e gwcalctyp<10, to reduce the number of frequencies used to evaluate the dielectric matrix from the (default) two to one frequency (omega=0) by setting nfreqre=1. This might be a good idea in case one is planning to use ppmodel>1. This will force the calculation of the screening on a single frequency (omega=0) and hence reduce memory and disk space requirement. The only draw back is that the user will not be able to perform self energy calculation using ppmodel=1, since in the last case the dielectric matrix calculated on two frequencies is required. If the user is not sure which ppmodel to use, then s/he is not advised to use this input variable. Using the default values, one must be able to get a screening file that can be used with any ppmodel.



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nfreqsp
Mnemonics: Number of FREQuencies for the SPectral function
Characteristic:
Variable type: integer parameter
Default is 0

Only relevant if optdriver=4, that is, sigma calculations.

nfreqsp defines the number of real frequencies used to calculate the spectral function of the GW Green's function.



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npwkss
Mnemonics: Number of PlaneWaves in the KSS file
Characteristic:
Variable type: integer parameter
Default is 0

This input variable is used for the preparation of a GW calculation: the GS run (where optdriver=1 and nbandkss/=0) should be followed with a run where optdriver=3. Also, if nbandkss=0, no use of npwkss.

npwkss defines the number of planewave components of the Kohn-Sham states to build the Hamiltonian, in the routine outkss.F90, and so, the size of the matrix, the size of eigenvectors, and the number of available states, to be stored in the abo_KSS file. If it is set to 0, then, the planewave basis set defined by the usual Ground State input variable ecut is used to generate the superset of all planewaves used for all k-points. Note that this (large) planewave basis is the same for all k-points.

Very important : for the time being, istwfk must be 1 for all the k-points.



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nkptgw
Mnemonics: Number of K-Points for GW corrections
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=4, that is, sigma calculations. This input variable was called "ngwpt" in versions before v4.3.

nkptgw gives the number of k-points for which the GW calculation must be done. It is used to dimension kptgw



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nomegasi
Mnemonics: Number of OMEGA(S) along the Imaginary axis
Characteristic: GW
Variable type: integer
Default is 12

Only relevant for sigma calculations in which the self-energy along the real axis is obtained by performing the analytic continuation from the imaginary axis to the full complex plane via the Pade approximant (optdriver=4 and gwcalctyp=x1).

nomegasi defines the number of frequency points used to sample the self-energy along the imaginary axis. The frequency mesh is linear and covers the interval between OMEGASIMIN=0.01 Hartree and omegasimax.



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nomegasf
Mnemonics: Number of OMEGA to evaluate the Spectral Function
Characteristic: GW, ENERGY
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3 and spmeth/=0, that is, screening calculations based on the spectral reprentation of the irreducible polarizability.

nomegasf defines the number of real frequencies used to describe the spectral function associated to the irreducible polarizability $\chi^{(0)}_{KS}$. The frequency mesh will cover the interval between 0 and the maximum (positive) transition energy between occupied and empty states. The delta function entering the expression defining the spectral function is approximated using two different methods according to the value of the spmeth input variable.

It is important to notice that an accurate description of the imaginary part of $\chi^{(0)}_{KS}$ requires an extremely dense frequency mesh. It should be kept in mind, however, that the memory required grows fast with the value of nomegasf.



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nomegasrd
Mnemonics: Number of OMEGA to evaluate the Sigma Real axis Derivative
Characteristic: GW
Variable type: integer parameter
Default is 9

Only relevant if optdriver=4, that is, sigma calculations.

The number of real frequencies around the KS energy where the self-energy Sigma is evaluated. From these values, the derivative of Sigma at the KS energy is numerically estimated through linear interpolation.



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npweps
Mnemonics: Number of PlaneWaves for EPSilon (the dielectric matrix)
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

npweps determines the size of the planewave set used to represent the independent-particle susceptibility $\chi^{(0)}_{KS}$, the dielectric matrix $\epsilon$ and its inverse.
See ecuteps (preferred over npweps) for more information.




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npwsigx
Mnemonics: Number of PlaneWaves for SIGma eXchange
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=4, that is, sigma calculations.

npwsigx determines the cut-off energy of the planewave set used to generate the exchange part of the self-energy operator.
See ecutsigx (preferred over npwsigx) for more information.




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npwwfn
Mnemonics: Number of PlaneWaves for WaveFunctioNs
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3 or 4, that is, screeening or sigma calculations.

npwwfn determines the size of the planewave set used to represent the wavefunctions in the formula that generates the independent-particle susceptibility $\chi^{(0)}_{KS}$.
See ecutwfn (preferred over nshwfn) for more information.




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nqptdm
Mnemonics: Number of Q-PoinTs for the Dielectric Matrix
Characteristic:
Variable type: integer parameter
Default is 0

Used only in the screening part, that is for optdriver=3.

If nqptdm is equal to 0, the set of q-points for computing the dielectric matrix is determined automatically considering all the possible differences between the k-points contained in the _KSS file. When nqptdm is non-zero, the list of q points is read from qptdm. This allows one to split the big calculation of all the dielectric matrices into smaller calculations that can be performed independently. The _SCR files generated in different runs can be merged thanks to the Mrgscr utility.



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nsheps
Mnemonics: Number of SHells for EPSilon (the dielectric matrix)
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3, that is, screening calculations.

nsheps determines the size of the planewave set used to represent the independent-particle susceptibility $\chi^{(0)}_{KS}$, the dielectric matrix $\epsilon$ and its inverse.
See ecuteps (preferred over nsheps) for more information.




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nshsigx
Mnemonics: Number of SHells for SIGma eXchange
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=4, that is, sigma calculations.

nshsigx determines the cut-off energy of the planewave set used to generate the exchange part of the self-energy operator.
See ecutsigx (preferred over nshsigx) for more information.




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nshwfn
Mnemonics: Number of SHells for WaveFunctioNs
Characteristic: GW
Variable type: integer parameter
Default is 0

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

nshwfn determines the number of shells of the planewave set used to represent the wavefunctions in the formula that generates the independent-particle susceptibility $\chi^{(0)}_{KS}$.
See ecutwfn (preferred over nshwfn) for more information.




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omegasimax
Mnemonics: OMEGA to evaluate Sigma along the Imaginary axis D: MAXimal value
Characteristic: GW, ENERGY
Variable type: real
Default is 50 eV

Only relevant for sigma calculations in which the self-energy along the real axis is obtained by performing the analytic continuation from the imaginary axis to the full complex plane via the Pade approximant (optdriver=4 and gwcalctyp=x1).

omegasimax defines the maximum frequency along the imaginary the axis. In conjunction with nomegasi, omegasimax uniquely defines the linear mesh employed to sample the self-energy along the imaginary axis.



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omegasrdmax
Mnemonics: OMEGA to evaluate the Sigma Real axis Derivative : MAXimal value
Characteristic: GW, ENERGY
Variable type: real
Default is 1.0 eV

Only relevant if optdriver=4, that is, sigma calculations.

The maximum distance from the KS energy where to evaluate Sigma. Sigma is evaluated at [KS_energy - maxomegasrd, KS_energy + maxomegasrd] sampled nomegasrd times.



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ppmfrq
Mnemonics: Plasmon Pole Model FReQuency
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0 Ha

Only relevant if optdriver=3 or 4, that is, screening calculations or sigma calculations. Only effective if GW corrections are evaluated using the plasmon-pole model of Godby-Needs (i.e ppmodel=1)

In the present status of the GW code, the convolution in frequency space defining the self-energy operator can be evaluated using two different approaches: numerical integration and plasmon-pole models.
Methods based on the numerical integration (contour deformation, analytic continuation) require the knowledge of the screened interaction for several frequencies. These approaches give the most accurate results but at the price of an increase in the CPU time required.
Alternately it is possible to approximate the dynamical behaviour of the screened interaction through simple analytical expressions, the so-called plasmon-pole models. In the plasmon-pole model proposes by Godby-Needs (ppmodel=1), the screening must be available at zero frequency, as well as at another frequency, imaginary, of the order of the plasmon frequency (the peak in the EELS spectrum). This information is used to derive the behaviour of the dielectric matrix for all the frequencies (complex). During the calculation of the screening, ppmfrq defines the imaginary frequency where the dielectric matrix is evaluated, in addition to the zero frequency. During the self-energy run, ppmfrq can be used to define the second frequency to be used to calculate the plasmon-pole parameters. This is particularly useful when the SCR file contains several frequencies along the imaginary axis. In this case the frequency whose value is the closest one to ppmfrq will be selected. Note that, if the plasmon-pole approximation is good, then, the choice of ppmfrq should have no influence on the final result. One should check whether this is the case. In general, the plasmon frequencies of bulk solids are of the order of 0.5 Hartree.




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ppmodel
Mnemonics: Plasmon Pole MODEL
Characteristic: GW
Variable type: integer parameter
Default is 1

Only relevant if optdriver=3 or 4, that is, screening calculations and self-energy calculations.

Please note the difference between ppmodel 1 and ppmodel 2,3,4. In the first case (ppmodel=1), the plasmon-pole parameters are determined in order to reproduce the behaviour of the dielectric matrix at two calculated frequencies: the static limit (omega=0) and the imaginary frequency defined by ppmfrq. In the last three cases, instead, the plasmon-pole parameters are found by using the dielectric matrix calculated only at omega=0 and enforcing the so-called f-sum rule. See also nfreqre.

Please note also that in the case of ppmodel 4, the plasmon energies are not simple mathematical parameters, but rather have a physical meaning (at least the lowest ones). Thus the calculated plasmon band structure (plasmon energy vs q vector) is reported in the output file for the lowest 10 bands.



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qptdm
Mnemonics: Q-PoinTs for the Dielectric Matrix
Characteristic: GW
Variable type: real array qptdm(3,nqptdm)
Default is 0. 0. 0. (for just one q-point)

Only relevant if optdriver=3, that is, screening calculations, and only if nqptdm/=0.

qptdm contains the set of q-points used in the screening part of ABINIT, instead of the automatic generation of the q points when nqptdm=0. These q points are given in terms of reciprocal space primitive translations (NOT in cartesian coordinates!). For further explanation, see the input variable nqptdm.



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rcut
Mnemonics: Radius of the CUT-off for coulomb interaction
Characteristic: GW
Variable type: real parameter
Default is 0.0d0

Truncation of the Coulomb interaction in real space. The meaning of rcut is governed by the cutoff shape option icutcoul.

If rcut is negative, the cutoff is automatically calculated so to enclose the same volume inside the cutoff as the volume of the solid.



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rhoqpmix
Mnemonics: RHO QuasiParticle MIXing
Characteristic: GW
Variable type: real parameter
Default is 1.0

For self-consistent GW runs, rhoqpmix sets the mixing coefficient between the new and the previous electronic densities. This mixing damps the spurious oscillations in the Hartree potential when achieving self-consistency. rhoqpmix is meaningful only when doing self-consistency on the wavefunctions with gwcalctyp >= 20.



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soenergy
Mnemonics: Scissor Operator ENERGY
Characteristic: GW, ENERGY
Variable type: real
Default is 0.0

Only relevant if optdriver=3, that is, screening calculations.

The Scissor operator energy to be added to unoccupied levels for the screening calculation. In some cases, it mimics a second iteration self-consistent GW calculation.



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spbroad
Mnemonics: SPectral BROADening
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.0

Only relevant if optdriver=3 and spmeth=2, that is, screening calculations based on the spectral reprentation of the irreducible polarizability in which the delta function is replace by the gaussian approximant whose standard deviation is given by spbroad.



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spmeth
Mnemonics: SPectral METHod
Characteristic: GW
Variable type: integer
Default is 0

Only relevant if optdriver=4, that is, sigma calculations.

The spmeth input variable defines the method used to calculate the irreducible polarizability $\chi^{(0)}_{KS}$.

By default $\chi^{(0)}_{KS}$ is calculated employing the Adler-Wiser expression (spmeth=0) with a CPU effort that scales linearly with the number of frequencies. This approach is convenient when few frequencies are required, and is usually used in conjunction with plasmon-pole models in which only one or two frequencies are calculated, according to the value of ppmodel.
Unfortunately a calculation based on the Adler-Wiser expression might be quite CPU demanding if the matrix elements of the self-energy operator are evaluated by performing numerically the convolution defining the sigma operator The integrand function, indeed, has poles above and below the real axis, and the screened interaction has to be evaluated on a dense frequency mesh in order to obtain accurate results.

In the spectral method (spmeth=1 or 2) the irreducible polarizability is expressed as the Hilbert transform of the imaginary part. The advantage in using this approach consists in the fact that, once the spectral function is known, the irreducible polarizability for an arbitrary frequency can be easily obtained through inexpensive integrations. On the other hand an accurate evaluation of the imaginary part requires a dense frequency mesh due to the presence of delta functions. Two different approaches can be used to approximate these delta functions thus allowing the use of affordable frequency grid.

Summarizing:





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symchi
Mnemonics: SYMmetryze \chi_o
Characteristic: DEVELOP, GW
Variable type: integer
Default is 0 FIXME TO BE CHANGED and moved to VARDEV

Only relevant if optdriver=3, that is, screening calculations.

The evaluation of the irreducible polarizability for a given q-point requires an integration over the Brillouin zone (BZ) which is approximated by a discrete sum over k-points. In principle the integrand function should be evaluated for each k-point in the BZ, however it is possible to reduce the number of points to be explicitly considered by taking advantage of symmetry properties. The development input variable symchi is used to choose between these two equivalent methods:





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symmorphi
Mnemonics: SYMMORPHIc symmetry operations
Characteristic: DEVELOP, GW
Variable type: integer parameter
Default is 1

With symmorphi=1, symmetry operations with a non-symmorphic vector are allowed. With symmorphi=0, they are not allowed. In the latter case, if the symmetry operations are specified in the input file, the code will stop and print an error message if a non-symmorphic vector is encountered. By contrast, if the symmetry operations are to be determined automatically (if nsym=0), then the set of symmetries will not include the non-symmorphic operations.

Note : this feature exist because in a previous status of the GW calculations, non-symmorphic symmetry operations could not be exploited. Thus, the k points were restricted to the IBZ. In order to prepare GW calculations, and to perform GW calculations, symmorphi=0 was to be used, together with nsym=0.



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symsigma
Mnemonics: SYMmetrization of SIGMA matrix elements
Characteristic: GW
Variable type: integer
Default is 0 (TO BE CHANGED according to gwcalctype

TO BE DESCRIBED



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vcutgeo
Mnemonics: V (potential) CUT-off GEOmetry
Characteristic: GW
Variable type: real array vcutgeo(3)
Default is 3*0.0d0

(No explicit documentation, please see https://listes-2.sipr.ucl.ac.be/abinit.org/arc/forum/2008-11/msg00087.html for the time being) vcutgeo is used in conjunction with icutcoul to specify the geometry used to truncate the Coulomb interaction as well as the particular approach to be used. It has a meaning only for the cylindrical symmetry (icutcoul=1) or in the case of surfaces icutcoul=2. For each geometry, two different definition of the cutoff region are available (see Phys. Rev. B 73, 233103 and Phys. Rev. B 73, 205119 for a complete description of the methods) In Beigi's method (Phys. Rev. B 73, 233103), the cutoff region is given by the Wigner-Seitz cell centered on the axis of the cylinder. The cutoff region is thus automatically defined by the unit cell and there's no need to specify When rcut. To define a cylinder along the z-axis use the following two lines. icutcoul 1 rprim 1 0 0 0 1 0 0 0 1 vcutgeo 0 0 1 Please note that Beigi's method is implemented only in the case if an orthorombic Bravais lattic. For hexagonal lattices, one has to use the method of Rozzi (Phys. Rev. B 73, 205119) In this case, the interaction is truncated in a finite cylinder. Contrarily to the first approach, here one has to specify both the radius of the cylinder with rcut as well as the length of the cylinder along the periodic dimension that should always be smaller than the extension of the Born von Karman box. The length of the cylinder is given in terms of the primitive vector along the periodic direction. For example, in order to define a finite cylinder along z of radius 2.5 Bohr and length 3*R3 icutcoul 1 rprim 1 0 0 0 1 0 0 0 1 vcutgeo 0 0 -3.0 # note the minus sign rcut 2.5 For surface calculations (icutcoul=2), vcutgeo is used to define the two periodic directions defining the surface. Also in this case two different techniques are available. In the method of Beigi, the (positive) non-zero components of vcutgeo define the periodic directions of the infinite surface. The interaction is truncated within a slab of width L where L is the length of the primitive vector of the lattice along the non-periodic dimension. For example: icutcoul 2 rprim 1 0 0 0 1 0 0 0 1 vcutgeo 1 1 0 It is also possible to define a finite surface by employing negative values For example: icutcoul 2 vcutgeo -3 -2 0 defines ....



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zcut
Mnemonics: Z-CUT
Characteristic: GW, ENERGY
Variable type: real parameter
Default is 0.1 eV = 3.67493260d-03Ha

Only relevant if optdriver=3 or 4, that is, screening or sigma calculations.

It is meant to avoid some divergencies that might occur during the evaluation of the Adler-Wiser expression of the irreducible polarizability (optdriver=3) or during the numerical treatment of the integrals defining the contribution to the self-energy matrix elements (optdriver=4). If the denominator becomes smaller than zcut, a small imaginary part (depending on zcut) is added, in order to avoid the divergence.
Ideally, one should make a convergence study decreasing the value of zcut for increasing number of k-points.




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